Aryl

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In the context of organic molecules, aryl refers to any functional group or substituent derived from a simple aromatic ring, may it be phenyl, thiophenyl, indolyl, etc (see IUPAC nomenclature). "Aryl" is used for the sake of abbreviation or generalization.

A simple aryl group is phenyl, C6H5; it is derived from benzene. The tolyl group, CH3C6H4, is derived from toluene (methylbenzene). The xylyl group, (CH3)2C6H3, is derived from xylene (dimethylbenzene).

A few different types of benzene derived aryl groups. From left to right: phenyl, benzyl, tolyl, o-xylyl.
A few different types of benzene derived aryl groups. From left to right: phenyl, benzyl, tolyl, o-xylyl.

Biaryls may display axial chirality.

[edit] See also


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